Distribution Pogil Answer Key Extension Questions: Maxwell Boltzmann
Students must perform a qualitative calculation to see the exponential effect.
Step-by-step calculation of the fraction ratio:
The Ratio of Rates: [ \frac\textRate at 400K\textRate at 300K = \frace^-15.03e^-20.05 = e^5.02 \approx 152 ] Students must perform a qualitative calculation to see
Conclusion: Even though the temperature increased by only 100K, the reaction rate is 150 times faster. The M-B extension question forces students to realize that kinetic energy distributions are mercilessly exponential.
POGIL Acceptable Answer: "The fraction of molecules with sufficient energy is exquisitely sensitive to temperature because (E_a / RT) appears in the exponent. A 100K increase reduces the exponent magnitude, yielding a 150-fold increase in reactive collisions." The Ratio of Rates: [ \frac\textRate at 400K\textRate
The statement is approximately true but not strictly true for a real gas.
a) (T_2) has a larger fraction above (E_a). The statement is approximately true but not strictly
b) Yes — increasing temperature increases the rate constant (k).
Correction: The catalyst changes the requirement (the Ea line), not the distribution of molecular speeds.